Showing posts with label Silk. Show all posts
Showing posts with label Silk. Show all posts

Silk | History, Production and consumption

Silk is one of the most precious textile fibres of animal origin, obtained from the flossy filament ejected by the silk worm of the butterfly Bombyx mori.

According to tradition, silk was discovered by a young Chinese empress, Hai Ling Shi, in 2640 BC. She noticed in her garden, on the branch of a mulberry tree, a small white cocoon, and brought it into the imperial palace to examine it more closely. Casually she dropped it into hot water and noted that a thin filament began to unwind. The court weaver was asked to do experiments with the new filmy fibre which kept unwinding as the empress pulled it; his trials resulted then in the weaving of the first silk dress.

silk

 

Silk processing aims at obtaining from cocoons a yarn as uniform as possible. It should be pointed out that it is the only continuous filament existing in nature. Raw silk consists by 60-70% of fibroin ( a white coloured protein), by 20-22% of sericin and, for the rest, of gummy substances, minerals and dyestuffs.

Before the pupa changes into a butterfly, cocoons are submitted to a first selection to eliminate the faulty ones and remove their outer layer (floss silk); then they are kept 16- 18 hours in drying ovens to cause the pupa's death and to eliminate moisture which would jeopardize their preservation.

The next operation is the cocoon sieving aimed at removing the residual floss silk, which may however be used together with other types of waste: imperfect cocoons, flock silk, filoselle, broken silk in schappe spinning.

A second sorting is then carried out to divide the cocoons into three size categories, which will be reeled separately because the smaller the filament diameter, the smaller the corresponding cocoon. After softening by immersion in warm water to facilitate the filament extraction, the cocoons are brushed to find the tail end of the filament and to remove from them the top layer of hair (flock silk). Once the tail ends are found, the cocoons are unwound until reeling begins to take place without difficulty. Degumming is followed by filament reeling, which produces a yarn composed of several filaments depending on the required yarn diameter. Once the yarn is twisted, it is wound with helical angle on reels, which are generally contained in special boxes which are closed and heated to enable yarn drying. The dried yarn is packed into skeins and put on the market under the denomination of raw or ecru silk.

Production and consumption

During the past 30 years, the world production of raw silk has steadily grown; this was however associated with a deep change of the production structure in terms of producing countries. In fact in 1970, with a silk world production amounting to abt. 40.000 tons, Japan accounted for the highest share with more than 50% (20,500 tons), followed by China (10,200), Soviet Union (3,000), South Korea (2,850), India (2,250). At that time, Italy still ranked among the producing countries with 310 tons.

On the contrary, today, the estimates of the International Silk Association show a global production of abt. 100,000 tons, where China is the leading producer with 70,000 tons (70%), whereas in Japan the production declined sharply to abt. 4,000 tons (4%). India, with 13,000 t, has therefore overtaken Japan and is now in second position, followed by CIS, Brazil and North Korea.

Among the "other" countries, let us mention Thailand, Turkey, South Korea, Vietnam, Indonesia and Paraguay.

Italy continues to rank among the leading importing countries of raw silk, which is converted, thanks to the skill of its domestic silk industry and to the high-tech Italian machines, into ply and schappe yarns, also blended with other fibres, into silk and bourette fabrics, scarfs, foulards and ties, which have made the Italian design renowned all over the world.

The main silk producing countries (1996)

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Silk REELING | RE-REELING TECHNIQUES

Silk Reeling is simply the unwinding of filaments from a group of cocoons in hot water bath on to a reel.

There are two methods of reeling a) Direct Reeling method on standard reels and b) Indirect method which includes preliminary reeling on small sized reels and transferring the reeled silk directly from the reels to standard sized reels on re-reeling machines.

Before reeling, cocoons have to pass various stages and production of quality silk depends upon various factors:

Purchase of Cocoons :

Selection of cocoons must be done carefully as any carelessness is this respect would spell serious losses to the reeling enterprise. Selective purchase of cocoons in an open market is extremely difficult, and becomes imperfect particularly in the absence of determined standards of quality for cocoons, and standard methods of testing for classifying cocoons into quality grades.

Cocoons should not be too flossy. Floss merely adds to the weight of cocoons when yielding silk for reeling. Cocoons should have well-rounded and firm ends and must not have too pronounced points. Well pointed ends are easy to detect because of their shape; thin ends can be detected by the lighter shade of colour at the end which when pressed yields readily, when floss is peeled off the cocoons, the surface must be fine grained and not deeply wrinkled.

Transporting Techniques :

The selected cocoons must be transported safely in perforated bamboo baskets or in loosely packed plastic crates, and must be transported during the cool hours. Packing the cocoons tightly and transporting them in the hot sun must always be avoided.

COCOON STIFLING & PRESERVATION

COCOON STIFLING:

Cocoons in their fresh condition with the pupae alive in them cannot be stored for a long time as the living pupae are soon transformed into moths. They are useless for reeling raw silk because the continuity of the bave in them is broken. Reeling cocoons, therefore, have to be subjected to a process of stifling with the object of killing the pupae inside without in anyway interfering with the structure of the silk shell around it. Cocoons can be stifled

by several methods but the popular methods in reeling industry are sun drying, steam stifling and hot air conditioning.

PRESERVATION:

Storage of cocoons is an important problem especially when the stiled cocoons have to be stored for a very long period. Complete desiccation of cocoons is a fairly satisfactory solution to the problem but even fully desiccated cocoons are liable to mould damage if the storage room is kept dry.

The other source of damage to cocoons in storage comes from the beetle pest, Dermestes lardarius. The following measures have to be followed for preservation of cocoons.

· Complete desiccation of cocoons before storing should be ensured.

· All care should be taken to see that the relative humidity in the store room does not rise above 70%.

· The store room must have good ventilation.

· Cocoons should be given regular and frequent turnings during the period
of storage and on no account should they be allowed to become damp.

· When fumigants are used care should be taken to keep the doors and windows open until all the traces of fumigants are removed

REELING & RE-REELING TECHNIQUES

Silk Reeling is simply the unwinding of filaments from a group of cocoons in hot water bath on to a reel.

There are two methods of reeling a) Direct Reeling method on standard reels and b) Indirect method which includes preliminary reeling on small sized reels and transferring the reeled silk directly from the reels to standard sized reels on re-reeling machines.

Systems of Reeling

There are two systems of reeling cocoons :

( i ) Floating System

( ii ) Sunken System

Floating System of Reeling

In floating system, the cocoons are cooked only to the extent the shell becomes wet, but is still impervious to water, so that they float in water when the cooked cocoons are put into the reeling basin. Floating system is associated with

1. Reeling of cooked cocoons which float in reeling basin.

2. High speed reeling.

3. High basin temperature.

4. Less number of reeling ends.

Sunken System of Reeling

In this system, the cooked cocoons sink in water at the time of reeling. In this system, not only the shell is cooked but in the process, the cocoon also gets filled with water inside to the extent of 97 to 98%, with the result, the cocoon becomes heavy and sinks in the reeling water. This system of reeling is associated with :

1. Reeling of cooked cocoons which sink under water in reeling basin.

2. Slow speed reeling.

3. Low basin temperature reeling.

4. Large number of reeling ends.

This system is suitable for superior quality cocoons like bivoltine. RE – REELING

Re – reeling is done to transfer the raw silk into standard sized hanks. The grant reeling helps in finding of broken ends of the thread and also its knotting. In grant reeling the hank is divided into several parts which can be kept separately by means of lacing. The ratio of the bevels determine the width of the diamond. For finer denier silk, more number of teeth have to be used. Re – reeling speed is almost double the reeling speed. So one end re-reeling will be enough to take the input of two end reeling. 13/24 bevel combination will produce 13 diamonds.

SKEINING

The standard size hanks from the swift are carefully examined for defects if any,it is laced and folded upon itself to form a skein with the help of skeining machine. The weight of the skeins varies from 50 g. to more that 100 g.

The skeins of raw silk are then made into books and bales are marketed later.

DIFFERENT SILK REELING DEVICES WITH ECONOMICS Reeling Devices:

There are three distinct reeling devices in mulberry sector namely

(a) Charka : It is a crude system of reeling. It is a simple hand driven device consists of a large cooking cum reeling pan where boiling water is kept.

(b)Cottage Basin System : It is improved over charka. It consists of separate cooking and reeling basin, where temperature is at boiling point only in the cooking basin, but reeling basin temperature is hardly 40 C.

(c) Multiend Basin System : It is a further improved version over the Cottage Basin and it is power driven. Boilers are installed and steam is used for cooking and reeling purpose and also for cocoon stifling in the special steam chambers.

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BYE – PRODUCTS USES

During the process of mulberry silk reeling, the different qualities of mulberry silk waste obtained as bye-products:

a) Waste from cocoons:Floss or Blaze, Spelaia (Italian) or Keba (Japan) Discarded cocoons, pierced, double, stained etc.,

Floss or Blaze: Floss silk or blaze also known as borra is the first part of the bave extruded by the worm for the frame work of the cocoon. Most of it is removed from the cocoons during their collection and rest while sorting. This can be used for noil spinning.

Discarded cocoons : This includes all cocoons found to be unreelable during sorting like :

Double Cocoons: which are jointly formed by the combination of two worms in the same shell and which due to the the interlocking of the continuous filaments cannot be reeled alongwith good cocoons. These cocoons are also employed for reeling ‘dupion silk’

Inferior Cocoons:The improperly built cocoons and those deformed in shape and also melted cocoons and other cocoons which become unfit for reeling due to some reason or the other.

b) Reeling waste :It may be filature, Cottage basin or charka silk waste

c) Winding waste: Re-reeling, winding or throwster’s waste, Weaving waste (Hard waste)

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composite spun silk yarns – Yarn structures

Effects of yarn structures in composite
spun silk yarns

The tensile properties of composite spun silk yarns and the compression properties of the fabrics were studied with a view to analyze the effects on yarn structure. Twin spun yarns, core spun yarns and doubled yarns were made by different spinning methods. It was then observed that the mechanical properties of composite yarns and fabrics varied according to the kinds of combined fibers. They were also considerably affected by the yarn structure, namely the number and direction of the twisting, even if the combination and the content of the fibers were constant. It was also found that the fabric made of the cotton/silk composite yarn might have a unique handling.
We studied the mechanical properties of the composite spun silk yarns and fabrics in previ­ous papers (Matsumoto et al., 1986, 1987), and since then we have continued studying them. Our final aim is to improve the stiffness of the spun silk fabrics whose soft handle is said to be a fatal defect, and to better the nature of spun silk yarn. The composite yarns are core spun yarns made from both a filament yarn in the core and the spun silk fiber as the skin layer. But there is a limitation in the produc­tion when the components used are filament yarn and staple fiber. Therefore, further study is required for composite yarns made from the combination of the staple fibers.
We tried making different composite yarns using staple fibers as a constant, and then examined the tensile properties of the yarns and the compression properties of the fabrics.

Materials and Methods
1. Materials
Table 1 lists the mean length of staple fibers used in the composite yarns. The combinations used in the yarn were : polyester/silk I, cotton/ silk I and silk II/silk I. The composite yarns contained about 70% silk I by weight, which were the twin spun yarn, the core spun yarn and the doubled yarn. The single yarns were also made of the fibers, in order to compare with the composite yarns. The British yarn count of all the yarns was 10, and the twist factor and the twist direction are listed in Table 2.
Furthermore, these yarns as the weft (density =17 picks/cm) were woven across the polyester filament warp (50 d/36 f, density=64 ends/cm) in a plain weave clip_image002
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2. Making of composite yarn
In the spun silk ring spinning frame which is shown in Fig. 1, two rovings are drafted on each drafting zone and are then twisted together to form a yarn. The drafting part is equipped with an apron device for the short staple fibers, namely, polyester, cotton and silk II. This yarn is called the twin spun yarn.
As shown in Fig. 2, a single yarn is used in the core, tension is provided by a magnet tensor applied to the front roller to combine with a roving as the skin layer, and then they are twisted together. This yarn is called the core spun yarn.
Furthermore, the doubled yarn is combined by twisting together two single yarns.
The cross sectional structure of yarns will be referred to in detail in the latter part of this paper and some examples are shown in Fig. 8.
3. Methods
The stress-strain curves of the yarns were measured using the constant-rate of elongation tester (Instron type) when the test length was 27 cm, the extension speed was 10 cm/min, and the number of testing times per yarn was 100. The compression properties of the fabrics were measured by the rolling method utilizing rolling friction from a solid cylinder (Shinohara and
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Go, 1961). As shown in Fig. 3, it is possible by this method to measure the rolling path when the solid cylinder rolls on the fabric at a constant initial velocity. The compressional modulus of fabric can be estimated from the size of the rolling path since the rolling path varies according to the stiffness of the fabric. The rolling path in the weft direction was measured using a sample that was 5 x 20 cm, and tested 10 times. And it was provided in the measurement that the angle between the slope and the horizontal plane of the sample was 1°, the length of the slope was 4 cm, and that the size of the roller, made of brass, was about 1.8 cm in diameter, 4 cm in length and 86.8 g in weight.
Results and Discussion
All the composite spun silk yarns used here were composed of silk I and the other staple fibers. Therefore, the produced yarns can be classified into three fibers, polyester, cotton and silk II. The yarns made from each of the fibers are single yarn, twin spun yarn, core spun yarn and doubled yarn. Using graphs let us tenta­tively connect the single yarn with a composite yarn by a broken line and connect the composite yarns with each other by a solid line. The vertical (y) axis varies according to each graph. The horizontal (x) axis of the graph is the arrangement of yarns, and it was set to cor­ respond with the number of twisting times because all twist directions were Z. As for the number of twisting times used to make a yarn, the single yarn was one, the twin spun yarn was one, the core spun yarn was two because the single yarn in the core had been twisted, and the doubled yarn was three for combining two single yarns.
Fig. 4 shows the count strength product from the produced yarns. The polyester/silk I com­posite yarn is smaller than the single polyester yarn, but the cotton/silk I composite yarn is larger than the cotton single yarn, and the silk II/silk I composite yarn is larger than the silk II single yarn. The strength of single yarns indicates a strength decrease in the following order, polyester, silk I, silk II and cotton. In general, the strength of a composite yarn is given by the sum of the strength generated by the two combined fibers. Thus, the composite yarns may be characterized as follows : In the case of polyester/silk I, a weak fiber of silk I
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is added to a strong single yarn of polyester. In the case of cotton/silk I or silk II/silk I, a strong fiber of silk I is added to a weak single yarn of cotton or silk II. Using this explanation, it is possible to understand the variations of the strength which compared the composite yarn with the single yarn.
Furthermore, the strength of composite yarns tends to decrease in the following order, the twin spun yarn, the core spun yarn and the doubled yarn. When the number of twisting times in the same direction is increased in the making of composite yarns, it brings about many twists in the yarn. It is known that as yarn twist is increased, yarn strength rises to a maximum value at some optimum twist and then falls. The tensile behavior of twisted staple yarns can be explained by the effects of fiber obliquity with respect to the yarn axis combined with the effects of fiber slippage (Bogdan, 1956). Therefore, it is found that the tendency to decrease is clearly due to the effects of fiber obliquity in the yarn.
Fig. 5 shows the elongation of the produced
yarns. The comparison between the composite yarns and the single yarns, in the problem of elongation can be solved by a similar method to that used for yarn strength. It can also be observed that the elongation of composite yarns
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increases in the following order, the twin spun yarn, the core spun yarn and the doubled yarn. Since the twisting required to make a yarn always has the same direction, the increase in the number of twisting times means that of the twist angle of fibers with respect to the yarn axis. Here, if the yarn extension is ay, the extension of the fiber in the yarn is Ef, and the twist angle is 0, the relation is ex­pressed by, Ey=ef/cos20 (Hearle et al., 1969). Consequently, it was found that the tendency to increase is clearly due to the increase in the twist angle.
The experimental results of the rolling path on the fabrics made from the cotton/silk I composite yarns and the single cotton yarn are shown in Fig. 6. Preliminary results using 150 rollings showed that after 70 rollings, the rolling path made a significant difference in the produced fabrics, but made little difference in each fabric. So, it is assumed that the fabrics have a con­stant value for the rolling path when the number of rollings is more than 70. We adopted a mean value of the rolling path of which the number of rollings is from 71 to 80. Fig. 7 shows the mean value of the rolling path in the produced fabrics. It is probably possible to compare the rolling path of the fabrics made from the composite yarn with that of the fabrics made from the single yarn as mentioned above. In the composite fabrics made from polyester/ silk I and silk II/silk I, the rolling path tends to decrease in the following order, the twin spun yarn, the core spun yarn and the doubled yarn. In proportion to the increase of the number of twisting times in the same direction, the fiber obliquity with respect to the yarn axis varies. The twist has a noticeable effect on the inward pressure of the yarn. As the twist is increased, the lateral force works for compress­ing the yarn and bringing the fibers closer together. So, the composite yarn becomes tighter. As the weft yarn becomes stiffer, the surface of the fabric also becomes rougher. Consequently, it seems that the rolling path has a decreasing tendency on the composite fabrics.
The mechanical properties of the composite yarns are as follows : For any combination used, the maximum value for strength and elongation is given by the twin spun yarn and the core spun yarn, respectively. But the maximum value for the rolling path is shown by the twin spun yarn, using polyester/silk I or silk II/silk I, and by the core spun yarn, using cotton/ silk I. That is to say, even if the kinds of combined fibers and the content percentage is constant, the form of the fiber and the yarn structure affect the handling of fabric. Specif­ically, it should be noted that the fabric made from the cotton/silk composite yarn has a u­nique handling characteristics in comparison with the other fabrics made from polyester/silk and silk/silk.
Furthermore, in order to obtain different handling, we tried combining the raw silk yarn as the filament yarn with the cotton/silk twin spun yarn as the staple fibers. It was done by joining the two production methods, namely the twin spun yarn and the core spun yarn. That is to say, by using the production method for the core spun yarn we tried inserting a raw silk yarn (21 d x 2, twist factor=0.3, Z) into the drafting part of the cotton fibers for making the twin spun yarn. The yarn contained about 8% raw silk, 28% cotton and 64% silk I be­cause the British yarn count was 10. We call this yarn the, 'core twin spun yarn'. The mechanical properties of the yarn and its fabric are shown in Table 3. The advantages of this yarn become clear when compared with the other composite yarns made from cotton 30%/ silk I 70% as shown in Figs. 4, 5 and 7. It was also found that the filament yarn is important in the composite yarn. Therefore, we must carry out further examinations of cotton/silk composite yarns including the core twin spun yarn.
Finally, some examples of yarn cross section are given in Fig. 8. (1) shows a single cotton yarn : the yarn lacks the coherence of fibers and has many spaces among the fibers. In the composite yarns using cotton 30%/silk I 70%, the yarn structures vary, shown in (2), (3) and (4). (2) shows a twin spun yarn : the component fibers are divided by a straight line. (3) shows a core spun yarn : the circular cross section is formed with the skin fiber and a single cotton yarn which has a circular form made by the single twist and is wrapped in the skin fiber. The staple fiber yarn was not given a high core tension because the elastic limit is so small. Therefore, it was very difficult to set the core yarn in the center of the yarn cross section. (4) shows a doubled yarn : the cross section is a distorted shape with a gap between the yarns, because each component yarn had already been twisted. Finally (5) shows a core twin spun yarn con­taining raw silk 8%/cotton 28%/silk I 64%: the cross section is similar in form to both those of the twin spun yarn and the core spun yarn above, however the spun silk fiber is twisted together with the cotton fiber wrapping around the raw silk yarn.
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Acknowledgement : We are grateful to our colleague Mr. Norishige Kayama for his coope­ration.
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YO-ICHI MATSUMOTO, IKUO TSUCHIYA and HIDEHIKO KYUMA
Faculty of Textile Science and Technology,
Shinshu University, Ueda 386

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